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Effect of curing temperature and architectural (monolayer and bilayer) of hybrid films modified with polyethylene glycol for the corrosion protection on tinplate

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Effect of curing temperature and architectural (monolayer and bilayer) of hybrid films modified with polyethylene glycol for the corrosion protection on tinplate

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Título Effect of curing temperature and architectural (monolayer and bilayer) of hybrid films modified with polyethylene glycol for the corrosion protection on tinplate
Autor Kunst, Sandra Raquel
Beltrami, Lílian Vanessa Rossa
Brandolt, Cristiane de Souza
Cardoso, Henrique Ribeiro Piaggio
Ortega Vega, Maria Rita
Baldin, Estela Knopp Kerstner
Menezes, Tiago Lemos
Malfatti, Célia de Fraga
Abstract Hybrid films obtained by a sol-gel process are based on two important reactions: hydrolysis and condensation. The condensation reaction is influenced by the curing temperature, since it induces the development of the intrinsic properties of the gel. The aim of this work is to coat tinplate, a substrate widely used in the packaging industry, with monolayered and bilayered hybrid films modified with polyethylene glycol and obtained through dip-coating. The results showed that the bilayered hybrid film obtained at 60°C had a higher layer thickness, and the best performance in the electrochemical assays, as well as the most hydrophobic character, in relation to the other samples. For the monolayered systems, the 90°C-cured system showed a lower layer thickness; however, this system showed a more compact, uniform and less porous layer, and presented better electrochemical impedance results, in comparison with the 60°C-cured samples.
Contido em Materials research : ibero-american journal of materials. São Carlos. Vol. 17, n. 4 (jul./ago. 2014), p. 1071-1081
Assunto Filmes híbridos
Folha de flandres
Revestimento
Sol-gel
[en] Bilayered systems
[en] Monolayered systems
[en] Temperature
[en] Tinplate
Origem Nacional
Tipo Artigo de periódico
URI http://hdl.handle.net/10183/115524
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