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Corrosion behavior of Ti and Ti6A14V in citrate buffers containing fluoride ions

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Corrosion behavior of Ti and Ti6A14V in citrate buffers containing fluoride ions

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Título Corrosion behavior of Ti and Ti6A14V in citrate buffers containing fluoride ions
Autor Schmidt, Anelise Marlene
Azambuja, Denise Schermann
Abstract The effect of fluoride ions concentration on the electrochemical behavior of Ti grade 2 and Ti6Al4V in citrate buffers was studied. Open circuit potential (OCP) measurements and voltammetric studies of the samples in the fluoride containing citrate buffers revealed a dissolution process when the pH falls below 5.0 and the NaF content is higher than 0.01 M. However, in citrate pH 7.6 the materials showed a passive behavior even in 0.1 M NaF. Some micrographs of Ti grade 2 obtained after longer immersion times in citrate pH 5.0 with 0.01 M NaF showed a surface attack. EIS (Electrochemical Impedance Sprectroscopy) data obtained at the OCP revealed that the film resistance decreases when the immersion time is increased in pH 5.0 containing 0.1 M NaF. In the citrate pH 7.6 the EIS data indicated a two-layer model of an oxide film consisting of a more compact inner layer and a porous outer layer. On the other hand, the EIS results in citrate pH 4.0 change significantly when the fluoride ions concentration increases from 0.01 to 0.05 M. The electrochemical data revealed that the corrosion behavior of Ti grade 2 and Ti6Al4V in the citrate buffers depends on the pH, the fluoride content and the exposure time.
Contido em Materials research: ibero-american journal of materials. São Carlos, SP. Vol. 13, no.1 (Jan./Mar. 2010), p. 45-50
Assunto Citrato
Corrosao
Fluoreto
Titanio
[en] Citrate
[en] Fluoride
[en] Ti
[en] Ti6Al4V
Origem Nacional
Tipo Artigo de periódico
URI http://hdl.handle.net/10183/29490
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